分析例
有機溶剤20成分
Conditions
Column:
|
Porapak™ QS 80/100
Porapak™ P 80/100
Porapak™ T 80/100
Porapak™ N 80/100
Gaskuropack 54 80/100
|
Analite:
|
1. Methanol
2. Ethanol
3. Acetonitrile
4. 2-Propanol
5. Acetone
6. Propionaldehyde
7. Acrylonitrile
8. 1-Propanol
9. Methyl ethyl ketone
10. Chloroform
11. Ethyl acetane
12. Methyl Cellosolve
13. Trichloroethylene
14. Benzene
15. Trichliroethylene
16. 2-Ethyl Cellosolve
17. N,N-dimethylformamide
18. Tetrachloroethylene
19. Isobutyl acetate
20. Chlorobenzene
|
Column Size:
|
SUS 2m × 1/8 O.D.
|
||
Carrier Gas:
|
He 20 mL/min
|
||
Injection:
|
Direct
250℃(Porapak™ QS、P、Gaskuropack 54)
190℃(Porapak™ N、T)
|
||
Injection Vol.:
|
0.2µL
|
||
Detection:
|
FID
250℃(Porapak™ QS、P、Gaskuropack 54)
190℃(Porapak™ N、T)
|
||
Sample Size:
|
Mixed evenly
|
※PoraPak™ はWaters Corporationの登録商標です。
保持時間比較 175℃ 一定
|
|
Porapak™
P |
Porapak™
QS |
Porapak™
N |
Porapak™
T |
Gaskuropack 54
|
---|---|---|---|---|---|---|
1.
|
Methanol
|
0.777
|
1.408
|
1.985
|
2.345
|
1.122
|
2.
|
Ethanol
|
0.958
|
2.328
|
3.440
|
3.869
|
1.682
|
3.
|
Acetonitrile
|
1.278
|
2.973
|
4.823
|
5.600
|
2.090
|
4.
|
2-Propanol
|
1.153
|
3.758
|
5.573
|
5.593
|
2.623
|
5.
|
Acetone
|
1.207
|
3.585
|
4.855
|
4.887
|
2.517
|
6.
|
Propionaldehyde
|
1.202
|
3.552
|
4.397
|
4.138
|
2.502
|
7.
|
Acrylonitrile
|
1.450
|
4.115
|
6.195
|
6.475
|
2.838
|
8.
|
1-Propanol
|
1.455
|
4.903
|
7.643
|
7.792
|
3.355
|
9.
|
Methyl ethyl ketone
|
1.840
|
7.488
|
10.132
|
9.412
|
5.117
|
10.
|
Chloroform
|
2.167
|
8.107
|
9.550
|
7.930
|
5.478
|
11.
|
Ethyl acetate
|
1.850
|
8.310
|
10.267
|
8.737
|
5.683
|
12.
|
Methyl Cellosolve
|
2.343
|
9.048
|
16.338
|
18.737
|
6.053
|
13.
|
Trichloroethane
|
2.497
|
11.878
|
12.177
|
8.855
|
8.032
|
14.
|
Benzene
|
2.882
|
12.255
|
12.690
|
9.815
|
8.388
|
15.
|
Trichloroethylene
|
3.058
|
13.357
|
13.575
|
10.118
|
9.060
|
16.
|
Ethyl Cellosolve
|
3.382
|
17.102
|
30.640
|
31.073
|
11.398
|
17.
|
N,N-dimethylformamide
|
5.562
|
21.285
|
42.135
|
55.678
|
13.938
|
18.
|
Tetrachloroethylene
|
5.363
|
28.435
|
26.115
|
17.203
|
19.338
|
19.
|
Isobutyl acetate
|
4.293
|
32.257
|
43.243
|
29.807
|
21.998
|
20.
|
Chlorobenzene
|
7.697
|
41.279
|
47.020
|
34.800
|
28.300
|
※PoraPak™ はWaters Corporationの登録商標です。
保持時間比較 40℃ - 10℃/min - 250℃(*:40℃ -10 ℃/min - 190℃)
|
|
Porapak™
P |
Porapak™
QS |
Porapak™
N* |
Porapak™
T* |
Gaskuropack 54
|
---|---|---|---|---|---|---|
1.
|
Methanol
|
5.130
|
8.020
|
10.995
|
11.978
|
6.788
|
2.
|
Ethanol
|
7.535
|
11.452
|
13.877
|
14.313
|
10.062
|
3.
|
Acetonitrile
|
8.977
|
12.497
|
15.092
|
15.680
|
11.025
|
4.
|
2-Propanol
|
9.120
|
13.917
|
15.924
|
15.857
|
12.477
|
5.
|
Acetone
|
9.181
|
13.593
|
15.238
|
15.190
|
12.188
|
6.
|
Propionaldehyde
|
9.100
|
13.520
|
14.816
|
14.512
|
12.100
|
7.
|
Acrylonitrile
|
9.950
|
14.188
|
14.249
|
16.347
|
12.677
|
8.
|
1-Propanol
|
10.308
|
15.115
|
17.415
|
17.402
|
15.592
|
9.
|
Methyl ethyl ketone
|
11.633
|
16.885
|
19.109
|
18.333
|
15.378
|
10.
|
Chloroform
|
12.001
|
17.169
|
18.677
|
17.303
|
15.562
|
11.
|
Ethyl acetate
|
11.835
|
17.302
|
19.190
|
17.873
|
15.858
|
12.
|
Methyl Cellosolve
|
12.491
|
17.635
|
23.112
|
24.205
|
16.092
|
13.
|
Trichloroethane
|
12.773
|
18.698
|
20.492
|
17.808
|
17.443
|
14.
|
Benzene
|
13.272
|
18.838
|
20.815
|
18.505
|
17.695
|
15.
|
Trichloroethylene
|
13.568
|
19.168
|
21.360
|
18.722
|
18.182
|
16.
|
Ethyl Cellosolve
|
14.165
|
19.993
|
31.658
|
30.938
|
19.758
|
17.
|
N,N-dimethylformamide
|
15.888
|
20.815
|
38.528
|
45.267
|
21.385
|
18.
|
Tetrachloroethylene
|
15.773
|
21.945
|
29.222
|
22.930
|
24.750
|
19.
|
Isobutyl acetate
|
15.208
|
21.998
|
38.500
|
29.578
|
26.055
|
20.
|
Chlorobenzene
|
17.150
|
23.497
|
41.480
|
32.522
|
30.058
|
※PoraPak™ はWaters Corporationの登録商標です。